User:Elaine Marie Robbins/Notebook/MOF/2012/06/06

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Owwnotebook icon.png Synthesizing PPF-18 Report.pngMain project page
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Methods

  1. Mix 7.9 mg TCPP, 8.9 mg Zn(NO3)2•6H2O, 4.2 mg DPNI, and 50 μL 1.0 M HCl in ethanol.
  2. Add to a mixture of 1.5 mL DEF and 0.5 mL ethanol.
  3. Sonicate to mix.
  4. Split into 2 vials:
    1. Vial 1: Add a small amount (< 1 mg) of PPF-18 crystals before cooling step
    2. Vial 2: Add a small amount (< 1 mg) of PPF-18 crystals before heating step.
  5. Heat in an oven at 80oC for 24 hr.
  6. Take UV/Vis and fluorescence data of PPF components.

Data

  • UV/Vis spectra of PPF components:
12-06-06 UVvis of PPF components.png


  • Fluorescence emission/excitation spectra of PPF components:
12-06-06 fluorescence of BPY.png
12-06-06 fluorescence of DPNI.png
12-06-06 fluorescence of Zn porphyrin.png