User:Elaine Marie Robbins/Notebook/MOF/2012/05/31

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Owwnotebook icon.png Filter PPF-18 and PPF-20 Report.pngMain project page
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Methods

Filter PPF-18 and PPF-20 Synthesized on 05/29/12

  1. Pour PPF-18/PPF-20 onto Reeve Angel #802 filter paper on a watch glass.
  2. Allow to filter for 1 hr.


Synthesize PPF-18 and PPF-20

  1. Synthesize 2 vials of PPF-18:
    1. Mix 7.9 mg TCPP, 8.9 mg Zn(NO3)2•6H2O, 4.2 mg DPNI, and 50 μL 1.0 M HCl in ethanol.
    2. Add to a mixture of 1.5 mL DEF and 0.5 mL ethanol.
    3. Sonicate to mix.
    4. Heat in an oven at 80oC for 24 hr.
  2. Synthesize 2 vials of PPF-20:
    1. Mix 7.9 mg TCPP, 8.9 mg Zn(NO3)2•6H2O, 16.8 mg DPNI, and 30 μL 1.0 M HCl in ethanol.
    2. Add to a mixture of 1.5 mL DMF and 0.5 mL ethanol.
    3. Sonicate to mix.
    4. Heat in an oven at 80oC for 24 hr.


Synthesize PPF-4 from PPF-20

  1. Mix 19.4 mg PPF-20, 6.9 mg BPY, 1.5 mL DEF, and 0.5 mg EtOH
  2. Swirl and allow to react for 3 hr.

Data

  • UV/vis data from PPF-18 solution after crystal removal:
12-05-31 UVvis of diluted PPF18 supernatant.png


  • Fluorescence data from PPF-18 solution after crystal removal (excited at 470 nm):
12-05-31 fluorescence (ex. 470 nm) of diluted PPF18 supernatant.png

Notes

Actual masses used for each PPF:

PPF-18 (1) PPF-18 (2) PPF-20 (1) PPF-20 (2)
TCPP 8.3 mg 7.9 mg 8.1 mg 7.8 mg
Zn(NO3)2•6H2O 9.6 mg 9.4 mg 9.0 mg 9.4 mg
DPNI 4.4 mg 4.1 mg 16.9 mg 17.3 mg