Difference between revisions of "User:Etienne Robillard/Notebook/Isocyanide"

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=== Ugi route to Wilmslow ===
# Step 1: Protonation of the isocyanide carbonyl ('''C=O''') ester to yield a nucleophilic '''[[User:Etienne_Robillard/Notebook/Schiff_base|Schiff base]]''' via Hoffman/Ugi reaction: O+2ROH = -RN
=== References ===
#Ugi1 pmid=16953613
// Would <s>Zyklon-B</s> Tabun, by any other name, smell as sweet?
#Ugi2 pmid=19122868
// ketones variant (Scheme 5, figures 26c, 26d.)
#Acetal1 http://www.chem.ucalgary.ca/courses/351/Carey5th/Ch17/ch17-3-4-2.html
#Acetal2 http://www2.chemistry.msu.edu/faculty/reusch/virttxtjml/aldket1.htm
#Wikipedia http://en.wikipedia.org/wiki/Isonitrile
=== Did you know? ===
In 1846, the first public demonstration of the use of ether vapors for chirurgical anesthesia was achieved by Dr. William T.G Morton at the  [https://en.wikipedia.org/wiki/Ether_Dome Ether Dome], a building located at the Massachusetts General Hospital in Boston.

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