Difference between revisions of "User:Ellen Petersen/Notebook/MOF Continued/2013/03/22"

From OpenWetWare
Jump to: navigation, search
Line 9: Line 9:
 
* 1.) Add solids 5,10,15,20- Tetrakis(4-carboxyl)-21H,23H-porphine  (TCPP) (.0079 g, .01 mmol),Zinc nitrate hexahydrate (.0089  g, .03 mmol, N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0168 g, .01 mmol)to small capped vial
 
* 1.) Add solids 5,10,15,20- Tetrakis(4-carboxyl)-21H,23H-porphine  (TCPP) (.0079 g, .01 mmol),Zinc nitrate hexahydrate (.0089  g, .03 mmol, N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0168 g, .01 mmol)to small capped vial
 
* 2.) Add 1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL)
 
* 2.) Add 1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL)
* 3.) Sealed and Sonicated to ensure homogeneity  
+
* 3.) Sealed and sonicated to ensure homogeneity  
 
* 4.) Heated to 80° C in an oven for 24 hours followed by a slow cooling to room temperature for 9 hours (Program 2)
 
* 4.) Heated to 80° C in an oven for 24 hours followed by a slow cooling to room temperature for 9 hours (Program 2)
 
_____________________________________________________________________________________________________________________________________________
 
_____________________________________________________________________________________________________________________________________________

Revision as of 11:33, 1 July 2013

Owwnotebook icon.png MOF: Tara <html><img src="/images/9/94/Report.png" border="0" /></html> Main project page
<html><img src="/images/c/c3/Resultset_previous.png" border="0" /></html>Previous entry<html>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;</html>Next entry<html><img src="/images/5/5c/Resultset_next.png" border="0" /></html>

PPF-18

  • 1.) Add solids 5,10,15,20- Tetrakis(4-carboxyl)-21H,23H-porphine (TCPP) (.0079 g, .01 mmol),Zinc nitrate hexahydrate (.0089 g, .03 mmol, N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0168 g, .01 mmol)to small capped vial
  • 2.) Add 1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL)
  • 3.) Sealed and sonicated to ensure homogeneity
  • 4.) Heated to 80° C in an oven for 24 hours followed by a slow cooling to room temperature for 9 hours (Program 2)

_____________________________________________________________________________________________________________________________________________ 03-27-2013

  • 5.) Vacuum Filtration
  • 6.) Run Powder X- Diffraction