Difference between revisions of "User:Ellen Petersen/Notebook/MOF Continued/2013/03/22"

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* 1.) Add solids 5,10,15,20- Tetrakis(4-carboxyl)-21H,23H-porphine  (TCPP) (.0079 g, .01 mmol),Zinc nitrate hexahydrate (.0089  g, .03 mmol, N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0168 g, .01 mmol)to small capped vial
 
* 1.) Add solids 5,10,15,20- Tetrakis(4-carboxyl)-21H,23H-porphine  (TCPP) (.0079 g, .01 mmol),Zinc nitrate hexahydrate (.0089  g, .03 mmol, N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0168 g, .01 mmol)to small capped vial
 
* 2.) Add 1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL)
 
* 2.) Add 1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL)
* 3.) Sealed and Sonicated to ensure homogeneity  
+
* 3.) Sealed and sonicated to ensure homogeneity  
 
* 4.) Heated to 80° C in an oven for 24 hours followed by a slow cooling to room temperature for 9 hours (Program 2)
 
* 4.) Heated to 80° C in an oven for 24 hours followed by a slow cooling to room temperature for 9 hours (Program 2)
 
_____________________________________________________________________________________________________________________________________________
 
_____________________________________________________________________________________________________________________________________________
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* 5.) Vacuum Filtration
 
* 5.) Vacuum Filtration
* 6.) Run Powder X- Diffraction (See Image Below)
+
* 6.) Run Powder X- Diffraction (See image below)
  
 +
[[Image:32713.png‎|200px|PPF-18]]
  
 
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Revision as of 11:11, 1 July 2013

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PPF-18

  • 1.) Add solids 5,10,15,20- Tetrakis(4-carboxyl)-21H,23H-porphine (TCPP) (.0079 g, .01 mmol),Zinc nitrate hexahydrate (.0089 g, .03 mmol, N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0168 g, .01 mmol)to small capped vial
  • 2.) Add 1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL)
  • 3.) Sealed and sonicated to ensure homogeneity
  • 4.) Heated to 80° C in an oven for 24 hours followed by a slow cooling to room temperature for 9 hours (Program 2)

_____________________________________________________________________________________________________________________________________________ 03-27-2013

  • 5.) Vacuum Filtration
  • 6.) Run Powder X- Diffraction (See image below)

PPF-18