User:Madeleine Y. Bee/Notebook/CHEM-581 Experimental Chemistry/2014/09/24: Difference between revisions
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|style="background-color: #EEE"|[[Image:BDLlogo_notext_lr.png|128px]]<span style="font-size:22px;"> CHEM 581: Experimental Chemistry</span> | |style="background-color: #EEE"|[[Image:BDLlogo_notext_lr.png|128px]]<span style="font-size:22px;"> CHEM 581: Experimental Chemistry</span> | ||
|style="background-color: #F2F2F2" align="center"| | |style="background-color: #F2F2F2" align="center"|[[File:Report.png|frameless|link={{#sub:{{FULLPAGENAME}}|0|-11}}]][[{{#sub:{{FULLPAGENAME}}|0|-11}}|Main project page]]<br />{{#if:{{#lnpreventry:{{FULLPAGENAME}}}}|[[File:Resultset_previous.png|frameless|link={{#lnpreventry:{{FULLPAGENAME}}}}]][[{{#lnpreventry:{{FULLPAGENAME}}}}{{!}}Previous entry]] }}{{#if:{{#lnnextentry:{{FULLPAGENAME}}}}|[[{{#lnnextentry:{{FULLPAGENAME}}}}{{!}}Next entry]][[File:Resultset_next.png|frameless|link={{#lnnextentry:{{FULLPAGENAME}}}}]]}} | ||
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==September 24, 2014== | ==September 24, 2014== | ||
===Procedures=== | ===Procedures=== | ||
====Completing Film Synthesis from Last Week==== | |||
#Warm 150mL of Sodium Sulfate Solution (see below for details) at 80C for 15 minutes | |||
#Place film in Sodium Sulfate Solution (see below for details) at 80C for 1 hour with gentle stirring | |||
#Warm 150mL of 1% HCl at 80C for 15 minutes | |||
#Place film in 1% HCl Solution (see below for details) at 80C for 30 minutes with gentle stirring | |||
#Place film in Sodium Bicarbonate Solution for 15 minutes at room temperature with gentle stirring | |||
====Make 10% Exchanged Clay Films==== | ====Make 10% Exchanged Clay Films==== | ||
*From our exchanged clay | *From our exchanged clay | ||
*#Add 7mL of water to | *#Add 7mL of water to 1.0028 g of 22,000MW polyvinyl alcohol and 0.1107 g of exchanged NaMT in a glass vial | ||
*#Stir the solution with constant heating at 75C until the polymer is dissolved and the clay is dispersed (~15 minutes) | *#Stir the solution with constant heating at 75C until the polymer is dissolved and the clay is dispersed (~15 minutes) | ||
*#Cool the solution to room temperature | *#Cool the solution to room temperature | ||
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*#Pour solution into a teflon dish to dry until the next class | *#Pour solution into a teflon dish to dry until the next class | ||
*From | *From MJJ's group exchanged clay | ||
*#Add 7mL of water to | *#Add 7mL of water to 1.0042 g of 22,000MW polyvinyl alcohol and 0.1101 g of exchanged NaMT (same ion as our group) in a glass vial | ||
*#Stir the solution with constant heating at 75C until the polymer is dissolved and the clay is dispersed (~15 minutes) | *#Stir the solution with constant heating at 75C until the polymer is dissolved and the clay is dispersed (~15 minutes) | ||
*#Cool the solution to room temperature | *#Cool the solution to room temperature | ||
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*#Pour solution into a teflon dish to dry until the next class | *#Pour solution into a teflon dish to dry until the next class | ||
====Atomic Absorption: | ====Atomic Absorption: Arsenic Solutions==== | ||
*Standard solutions: | *Standard solutions: | ||
**0ppm | **0ppm | ||
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**40ppm | **40ppm | ||
**50 ppm | **50 ppm | ||
*Sample dilutions: | **Note: all standard solutions made by James and Eleni | ||
*Sample dilutions (up to 10mL): | |||
**150 ppm solutions | |||
**5x dilution (~30 ppm): (1x)(V)=(1/5x)(10mL) | |||
***2 mL in 10 mL | |||
**100 ppm solutions | |||
**4x dilution (~20 ppm): (1x)(V)=(1/4x)(10mL) | |||
***2.5 mL in 10 mL | |||
**50 ppm solutions | |||
**No dilution | |||
*Note: AA detector broken, this is will be continued at a later date | |||
====Soaking Films in Rhodamine 6G Dye==== | |||
{| {{table}} | |||
| align="center" style="background:#f0f0f0;"|'''Film''' | |||
| align="center" style="background:#f0f0f0;"|'''Solution''' | |||
| align="center" style="background:#f0f0f0;"|'''Vial mass''' | |||
| align="center" style="background:#f0f0f0;"|'''Vial + film mass''' | |||
| align="center" style="background:#f0f0f0;"|'''Film mass''' | |||
|- | |||
| PVA film|| 20 uM R6G|| 13.0803 g|| 13.1813 g|| 0.101 g | |||
|- | |||
| || 10 uM R6G|| 13.0713 g|| 13.1497 g|| 0.0784 g | |||
|- | |||
| || 1 uM R6G||13.0403 g|| 13.1337 g|| 0.0934 g | |||
* | |- | ||
| PVA-Clay film|| 20 uM R6G|| 13.0828 g|| 13.2554 g|| 0.1726 g | |||
|- | |||
| || 10 uM R6G|| 12.9552 g|| 13.0732 g|| 0.118 g | |||
|- | |||
| || 1 uM R6G|| 13.0198 g|| 13.1377 g|| 0.1179 g | |||
|} | |||
*Dilutions done by James and Eleni | |||
*Each film soaked in 10 mL R6G solution | |||
Latest revision as of 00:20, 27 September 2017
CHEM 581: Experimental Chemistry | Main project page Previous entry Next entry | |||||||||||||||||||||||||||||||||||
September 24, 2014ProceduresCompleting Film Synthesis from Last Week
Make 10% Exchanged Clay Films
Atomic Absorption: Arsenic Solutions
Soaking Films in Rhodamine 6G Dye
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