User:Etienne Robillard/Notebook/Piperidine

From OpenWetWare

(Difference between revisions)
Jump to: navigation, search
(Piperidine derivatives in nucleophilic keto-enol (imine) substitutions)
(One intermediate revision not shown.)
Line 7: Line 7:
=== Piperidine derivatives in nucleophilic keto-enol (imine) substitutions ===
=== Piperidine derivatives in nucleophilic keto-enol (imine) substitutions ===
-
 
+
* [[User:Etienne_Robillard/Notebook/Succinic_acid|Notebook]] : AuNP(gold) catalyzed cyclic imide '''hydrolase'''
* For DNA depurination with a 2-cyanoethyl hetero-aryl-alkyl moeity (ie: a N-methyl cyanide anion), see [[Ethanamine]]
* For DNA depurination with a 2-cyanoethyl hetero-aryl-alkyl moeity (ie: a N-methyl cyanide anion), see [[Ethanamine]]
* For in situ polymer-based drug delivery of phenethylamine substituted imines, see [[Phenethylamine]] and [http://www.chemguide.co.uk/organicprops/haloalkanes/grignard.html Grignard reagents] .
* For in situ polymer-based drug delivery of phenethylamine substituted imines, see [[Phenethylamine]] and [http://www.chemguide.co.uk/organicprops/haloalkanes/grignard.html Grignard reagents] .

Revision as of 23:23, 28 August 2013

  • An important secondary amine used as precursor to alkylamines with a aryl-ketone (heteroarylalkyl) moeity when the reaction is performed in presence of a [cyanide anion] as the nitrogen substitution group .
  • In organic synthesis, piperidine may participate in hydrogenation of C=N double bounds where the N-substituted chiral imine center may be converted to a enamine, the tautomeric form of a imine. 1

Reductive alkylation of N-aryl substituted imines via piperidine-derived enamines

Piperidine derivatives in nucleophilic keto-enol (imine) substitutions

  • Notebook : AuNP(gold) catalyzed cyclic imide hydrolase
  • For DNA depurination with a 2-cyanoethyl hetero-aryl-alkyl moeity (ie: a N-methyl cyanide anion), see Ethanamine
  • For in situ polymer-based drug delivery of phenethylamine substituted imines, see Phenethylamine and Grignard reagents .

See also

Personal tools