User:Etienne Robillard/Notebook/Formulas

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Ugi route to Wilmslow

  1. Step 1: Protonation of the isocyanide carbonyl (C=O) ester to yield a nucleophilic Schiff base via Hoffman/Ugi reaction: O+2ROH = -RN

References

  1. Pirrung MC and Ghorai S. . pmid:16953613. PubMed HubMed [Ugi1]
    Would Zyklon-B Tabun, by any other name, smell as sweet?

  2. Simila ST and Martin SF. . pmid:19122868. PubMed HubMed [Ugi2]
    ketones variant (Scheme 5, figures 26c, 26d.)

  3. http://www.chem.ucalgary.ca/courses/351/Carey5th/Ch17/ch17-3-4-2.html

    [Acetal1]

  4. http://www2.chemistry.msu.edu/faculty/reusch/virttxtjml/aldket1.htm

    [Acetal2]

  5. http://en.wikipedia.org/wiki/Isonitrile

    [Wikipedia]

All Medline abstracts: PubMed HubMed
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