User:Etienne Robillard/Notebook/Acetaldehyde

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* Ethanamine is the tautomeric form of PVA (PVOH), a acetaldehyde derived imine group... An alternative name is "aminoacetaldehyde dimethyl acetal". [http://webbook.nist.gov/cgi/inchi/InChI=1S/C4H11NO2/c1-6-4(3-5)7-2/h4H,3,5H2,1-2H3 1]
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==Important Facts about Ethanamine (Acetaldehyde)==
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* Ethanamine (Acetaldehyde) is the tautomeric form of important N-substituted [[User:Etienne_Robillard/Notebook/Schiff_base|Schiff bases]] including PVA (Polyvinyl acetate) and [[User:Etienne_Robillard/Notebook/Acetonitrile|Acetonitrile]].  
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* An alternative name is "aminoacetaldehyde dimethyl acetal".  
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==Experimental==
* When [[Chloroform]] or [[DCM]] is used as a reactant gas, unstable ethanamine species may be converted to '''HN3''' vapors in situ via the Schmidt route. [2, 3, 4]  
* When [[Chloroform]] or [[DCM]] is used as a reactant gas, unstable ethanamine species may be converted to '''HN3''' vapors in situ via the Schmidt route. [2, 3, 4]  
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* InChI=1S/C4H11NO2/c1-6-4(3-5)7-2/h4H,3,5H2,1-2H3
 
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== See also ==
== See also ==
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* [[User:Etienne_Robillard/Notebook/Chloroform|Chloroform]]
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* [[Glutaraldehyde_(Pentanedial) Glutaraldehyde]]
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* [[Chloroform]]
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* [[Phosgene]]
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== References ==
== References ==
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# Investigations into the Chemistry of Thermodynamically Unstable Species. The Direct Polymerization of Vinyl Alcohol, the Enolic Tautomer of Acetaldehyde. Anna K. Cederstav and Bruce M. Novak. Journal of the American Chemical Society, 1994, Volume 116, Pages 4073-4074
# Investigations into the Chemistry of Thermodynamically Unstable Species. The Direct Polymerization of Vinyl Alcohol, the Enolic Tautomer of Acetaldehyde. Anna K. Cederstav and Bruce M. Novak. Journal of the American Chemical Society, 1994, Volume 116, Pages 4073-4074
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# http://en.wikipedia.org/wiki/Schmidt_reaction
 
# http://www2.chemistry.msu.edu/faculty/reusch/VirtTxtjml/rearrang.htm
# http://www2.chemistry.msu.edu/faculty/reusch/VirtTxtjml/rearrang.htm
# http://www.cdc.gov/niosh/ershdb/EmergencyResponseCard_29750012.html
# http://www.cdc.gov/niosh/ershdb/EmergencyResponseCard_29750012.html
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# https://www.sciencemadness.org/whisper/viewthread.php?tid=15190

Current revision

Contents

Important Facts about Ethanamine (Acetaldehyde)

  • Ethanamine (Acetaldehyde) is the tautomeric form of important N-substituted Schiff bases including PVA (Polyvinyl acetate) and Acetonitrile.
  • An alternative name is "aminoacetaldehyde dimethyl acetal".

Experimental

  • When Chloroform or DCM is used as a reactant gas, unstable ethanamine species may be converted to HN3 vapors in situ via the Schmidt route. [2, 3, 4]

See also

References

  1. Investigations into the Chemistry of Thermodynamically Unstable Species. The Direct Polymerization of Vinyl Alcohol, the Enolic Tautomer of Acetaldehyde. Anna K. Cederstav and Bruce M. Novak. Journal of the American Chemical Society, 1994, Volume 116, Pages 4073-4074
  2. http://www2.chemistry.msu.edu/faculty/reusch/VirtTxtjml/rearrang.htm
  3. http://www.cdc.gov/niosh/ershdb/EmergencyResponseCard_29750012.html
  4. https://www.sciencemadness.org/whisper/viewthread.php?tid=15190
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