User:Etienne Robillard/Notebook/Acetaldehyde

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* Ethanamine is the tautomeric form of PVA (PVOH), a acetaldehyde derived imine group... An alternative name is "aminoacetaldehyde dimethyl acetal". [http://webbook.nist.gov/cgi/inchi/InChI=1S/C4H11NO2/c1-6-4(3-5)7-2/h4H,3,5H2,1-2H3 1]
* Ethanamine is the tautomeric form of PVA (PVOH), a acetaldehyde derived imine group... An alternative name is "aminoacetaldehyde dimethyl acetal". [http://webbook.nist.gov/cgi/inchi/InChI=1S/C4H11NO2/c1-6-4(3-5)7-2/h4H,3,5H2,1-2H3 1]
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* When [[Chloroform]] or [[DCM]] is used as a reactant gas, unstable ethanamine species may be converted to '''HN3''' vapors in situ via the Schmidt route. [2, 3, 4]  
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* When [[Chloroform]] or [[DCM]] is used as a reactant gas, unstable ethanamine species may be converted to '''HN3''' vapors in situ via the Schmidt route. [2, 3, 4, 5]  
* InChI=1S/C4H11NO2/c1-6-4(3-5)7-2/h4H,3,5H2,1-2H3
* InChI=1S/C4H11NO2/c1-6-4(3-5)7-2/h4H,3,5H2,1-2H3
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# http://www2.chemistry.msu.edu/faculty/reusch/VirtTxtjml/rearrang.htm
# http://www2.chemistry.msu.edu/faculty/reusch/VirtTxtjml/rearrang.htm
# http://www.cdc.gov/niosh/ershdb/EmergencyResponseCard_29750012.html
# http://www.cdc.gov/niosh/ershdb/EmergencyResponseCard_29750012.html
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# https://www.sciencemadness.org/whisper/viewthread.php?tid=15190

Revision as of 07:47, 15 February 2013

  • Ethanamine is the tautomeric form of PVA (PVOH), a acetaldehyde derived imine group... An alternative name is "aminoacetaldehyde dimethyl acetal". 1
  • When Chloroform or DCM is used as a reactant gas, unstable ethanamine species may be converted to HN3 vapors in situ via the Schmidt route. [2, 3, 4, 5]
  • InChI=1S/C4H11NO2/c1-6-4(3-5)7-2/h4H,3,5H2,1-2H3

See also

References

  1. Investigations into the Chemistry of Thermodynamically Unstable Species. The Direct Polymerization of Vinyl Alcohol, the Enolic Tautomer of Acetaldehyde. Anna K. Cederstav and Bruce M. Novak. Journal of the American Chemical Society, 1994, Volume 116, Pages 4073-4074
  2. http://en.wikipedia.org/wiki/Schmidt_reaction
  3. http://www2.chemistry.msu.edu/faculty/reusch/VirtTxtjml/rearrang.htm
  4. http://www.cdc.gov/niosh/ershdb/EmergencyResponseCard_29750012.html
  5. https://www.sciencemadness.org/whisper/viewthread.php?tid=15190
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