User:Ellen Petersen/Notebook/MOF Continued/2013/03/22: Difference between revisions
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|style="background-color: #EEE"|[[Image:owwnotebook_icon.png|128px]]<span style="font-size:22px;"> MOF: Tara</span> | |style="background-color: #EEE"|[[Image:owwnotebook_icon.png|128px]]<span style="font-size:22px;"> MOF: Tara</span> | ||
|style="background-color: #F2F2F2" align="center"| | |style="background-color: #F2F2F2" align="center"|[[File:Report.png|frameless|link={{#sub:{{FULLPAGENAME}}|0|-11}}]][[{{#sub:{{FULLPAGENAME}}|0|-11}}|Main project page]]<br />{{#if:{{#lnpreventry:{{FULLPAGENAME}}}}|[[File:Resultset_previous.png|frameless|link={{#lnpreventry:{{FULLPAGENAME}}}}]][[{{#lnpreventry:{{FULLPAGENAME}}}}{{!}}Previous entry]] }}{{#if:{{#lnnextentry:{{FULLPAGENAME}}}}|[[{{#lnnextentry:{{FULLPAGENAME}}}}{{!}}Next entry]][[File:Resultset_next.png|frameless|link={{#lnnextentry:{{FULLPAGENAME}}}}]]}} | ||
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* 1.) Add solids 5,10,15,20- Tetrakis(4-carboxyl)-21H,23H-porphine (TCPP) (.0079 g, .01 mmol),Zinc nitrate hexahydrate (.0089 g, .03 mmol, N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0168 g, .01 mmol)to small capped vial | * 1.) Add solids 5,10,15,20- Tetrakis(4-carboxyl)-21H,23H-porphine (TCPP) (.0079 g, .01 mmol),Zinc nitrate hexahydrate (.0089 g, .03 mmol, N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0168 g, .01 mmol)to small capped vial | ||
* 2.) Add 1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL) | * 2.) Add 1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL) | ||
* 3.) Sealed and | * 3.) Sealed and sonicated to ensure homogeneity | ||
* 4.) Heated to 80° C in an oven for 24 hours followed by a slow cooling to room temperature for 9 hours (Program 2) | * 4.) Heated to 80° C in an oven for 24 hours followed by a slow cooling to room temperature for 9 hours (Program 2) | ||
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* 5.) Vacuum Filtration | * 5.) Vacuum Filtration | ||
* 6.) Run Powder X- Diffraction | * 6.) Run Powder X- Diffraction (See image below) | ||
[[Image:32713.png|200px|PPF-18]] | |||
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Latest revision as of 22:53, 26 September 2017
 MOF: Tara
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PPF-18
_____________________________________________________________________________________________________________________________________________ 03-27-2013
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