PPF-18 w/ various metals
- 1.) Add Zinc nitrate hexahydrate (.0072796 g, .03 mmol), N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0042 g, .01 mmol),1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL), & 100μl Iron Chloride Porphyrin Mix to a small capped vial labeled PPF-18 w/ Iron Chloride
- 2.) Add Zinc nitrate hexahydrate (.002488 g, .03 mmol), N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0042 g, .01 mmol),1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL), & 100μl Cobalt Acetate Porphyrin Mix to a small capped vial labeled PPF-18 w/ Cobalt Acetate
- 3.) Add Zinc nitrate hexahydrate (.006412 g, .03 mmol), N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0042 g, .01 mmol),1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL), & 100μl Cupric Acetate Porphyrin Mix to a small capped vial labeled PPF-18 w/ Cupric Acetate
- 4.) Add Zinc nitrate hexahydrate (.0068095 g, .03 mmol), N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0042 g, .01 mmol),1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL), & 100μl Nickel Nitrate Porphyrin Mix to a small capped vial labeled PPF-18 w/ Nickel Nitrate
- 5.) All vials are sealed and sonicated to ensure homogeneity
- 6.) Heated to 80° C in an oven for 24 hours followed by a slow cooling to room temperature for 9 hours (Program 2)
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08--2013
- 9.) Vacuum Filtration
- 10.) Powder X-Ray Diffraction (see images below)
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MOF:Ellen
