User:Elaine Marie Robbins/Notebook/MOF/2012/05/29

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Synthesize PPF-18 and PPF-20 Main project page
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Methods

  1. Synthesize 2 vials of PPF-18:
    1. Mix 7.9 mg TCPP, 8.9 mg Zn(NO3)2•6H2O, 4.2 mg DPNI, and 50 μL 1.0 M HCl in ethanol.
    2. Add to a mixture of 1.5 mL DEF and 0.5 mL ethanol.
    3. Sonicate to mix.
    4. Heat in an oven at 80oC for 24 hr.
  2. Synthesize 2 vials of PPF-20:
    1. Mix 7.9 mg TCPP, 8.9 mg Zn(NO3)2•6H2O, 16.8 mg DPNI, and 30 μL 1.0 M HCl in ethanol.
    2. Add to a mixture of 1.5 mL DMF and 0.5 mL ethanol.
    3. Sonicate to mix.
    4. Heat in an oven at 80oC for 24 hr.

Notes

Actual masses used for each PPF:

PPF-18 (1) PPF-18 (2) PPF-20 (1) PPF-20 (2)
TCPP 8.5 mg 8.4 mg 8.3 mg 8.3 mg
Zn(NO3)2•6H2O 9.2 mg 9.0 mg 8.5 mg 9.3 mg
DPNI 4.3 mg 4.1 mg 16.9 mg 17.4 mg


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