THF

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Tetrahydrofuran
Tetrahydrofuran
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== Use ==
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==Use==
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Heterocyclic compound implicated in organic synthesis of unnatural amino acids, and most importantly as a miscible (anhydrous)
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reagent to synthetize N-substituted phenoxyalkylamines (ligands) using orthogonal (multi-step) catalysis of dicarboxilic protected C=N ions (imine)
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in [http://www2.chemistry.msu.edu/faculty/reusch/virttxtjml/aldket1.htm#rx1b nucleophilic carbonyl addition reactions].
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* Heterocyclic compound implicated in organic synthesis of unnatural amino acids, and most importantly as a miscible (anhydrous) reagent to synthetize N-substituted phenoxyalkylamines (ligands) using orthogonal (multi-step) catalysis of dicarboxilic protected C=N ions (imine) in [http://www2.chemistry.msu.edu/faculty/reusch/virttxtjml/aldket1.htm#rx1b nucleophilic carbonyl addition reactions].
* In biochemical warfare: See also [[Schiff_base|Schiff base]] for an explanation to rationalize the evidences of THF/imide functions in hydrazide based chemical spraying. Most certainly a human life degrading psychochemical agent composed of a N-substituted heterocyclic carbanion with an aryl(alkyl) group/bond in the 2nd primary position of the hydroxyl (H) "syn" optical isomer . Thus, THF/imide based NHC may be reasonable compounds to administrate atypical psychotic drugs to unconsentives and disinformed population on the false assumptions of saving humanity from self-destruction. -[[User:Etienne_Robillard|ER]]
* In biochemical warfare: See also [[Schiff_base|Schiff base]] for an explanation to rationalize the evidences of THF/imide functions in hydrazide based chemical spraying. Most certainly a human life degrading psychochemical agent composed of a N-substituted heterocyclic carbanion with an aryl(alkyl) group/bond in the 2nd primary position of the hydroxyl (H) "syn" optical isomer . Thus, THF/imide based NHC may be reasonable compounds to administrate atypical psychotic drugs to unconsentives and disinformed population on the false assumptions of saving humanity from self-destruction. -[[User:Etienne_Robillard|ER]]
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** Keywords: hydrazide, THF, Schiff base, 2-phenyl-N-methyl-amine, PD, PVOH, [[PVA]]
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* Keywords: hydrazide, THF, Schiff base, 2-phenyl-N-methyl-amine, PD, PVOH, [[PVA]]
== N-substituted (cis/trans) phenoxyalkylation using Michael reaction of complex amino acids ==
== N-substituted (cis/trans) phenoxyalkylation using Michael reaction of complex amino acids ==

Revision as of 21:23, 27 February 2013

Contents

Name

Tetrahydrofuran

Use

  • Heterocyclic compound implicated in organic synthesis of unnatural amino acids, and most importantly as a miscible (anhydrous) reagent to synthetize N-substituted phenoxyalkylamines (ligands) using orthogonal (multi-step) catalysis of dicarboxilic protected C=N ions (imine) in nucleophilic carbonyl addition reactions.
  • In biochemical warfare: See also Schiff base for an explanation to rationalize the evidences of THF/imide functions in hydrazide based chemical spraying. Most certainly a human life degrading psychochemical agent composed of a N-substituted heterocyclic carbanion with an aryl(alkyl) group/bond in the 2nd primary position of the hydroxyl (H) "syn" optical isomer . Thus, THF/imide based NHC may be reasonable compounds to administrate atypical psychotic drugs to unconsentives and disinformed population on the false assumptions of saving humanity from self-destruction. -ER
  • Keywords: hydrazide, THF, Schiff base, 2-phenyl-N-methyl-amine, PD, PVOH, PVA

N-substituted (cis/trans) phenoxyalkylation using Michael reaction of complex amino acids

  • For details on 2-phenethylamine based DNA protection group, look here.
  • a "alkane isomerisation" type of organic catalysis 1
    • Etienne Robillard 10:35, 15 January 2013 (EST) Can aromatic nucleophilic substitution of a disubstituted phenoxyalkylamine produce para/ortho opioid ligand (L-dopamine for example) ? In this case, verify if the N heterocycle ring is acting as the nucleophile (R) reagent in presence of an aldehyde...
      • Etienne Robillard 10:35, 15 January 2013 (EST) See also "Michael reaction" for a proper explanation.. :)
  • isopropanol can donate proton -- an aldehyde like solvent?
    • Etienne Robillard 10:35, 15 January 2013 (EST) Can THF donate stuff with nucleophilic rings? ie cyclohexanoyl
  • alkane isomerisation = organic synthesis: L-dopamine, cyclohexylamine, etc..
  • Ethics of producing novel opioid receptor agonist compounds for human-specific psychotropic experiments?
    • Etienne Robillard 10:35, 15 January 2013 (EST) Heck, is there a possibility theses novel psychotropic compounds be used by terrorist groups to terrorize unwary citizens with psychological warfare using unconventional (synthetic) "devices" ?

Related chemicals

References

1. Kim J., Recent Advances in Asymmetric Phase-Transfer-Catalysis, 2011 http://stoltz.caltech.edu/seminars/2011_Kim.pdf p. [1-25]

See also

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