THF
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reagent to synthetize N-substituted phenoxyalkylamines (ligands) using orthogonal (multi-step) catalysis of dicarboxilic protected C=C ions (amines) | reagent to synthetize N-substituted phenoxyalkylamines (ligands) using orthogonal (multi-step) catalysis of dicarboxilic protected C=C ions (amines) | ||
in liquid phase PTC/Ion chromatography. | in liquid phase PTC/Ion chromatography. | ||
| + | |||
| + | == N-substituted (cis/trans) phenoxyalkylation using Michael reaction of complex amino acids == | ||
| + | |||
| + | * a "alkane isomerisation" type of organic catalysis ? [http://chemwiki.ucdavis.edu/Organic_Chemistry/Organic_Chemistry_With_a_Biological_Emphasis/Chapter_14:_Reactions_with_stabilized_carbanion_intermediates_II/Section_14.2:_Variations_on_the_Michael_reaction 1] | ||
| + | * isopropanol can donate proton -- an aldehyde like solvent? | ||
| + | * alkane isomerisation = organic synthesis: L-dopamine, cyclohexylamine, etc.. | ||
| + | * ethics of producing synthetic opioid receptor agonist compounds for human-specific psychotropic experiments? | ||
== Related chemicals == | == Related chemicals == | ||
Revision as of 11:35, 14 January 2013
Contents |
Name
Tetrahydrofuran
Use
Heterocyclic compound implicated in organic synthesis of unnatural amino acids, and most importantly as a miscible (anhydrous) reagent to synthetize N-substituted phenoxyalkylamines (ligands) using orthogonal (multi-step) catalysis of dicarboxilic protected C=C ions (amines) in liquid phase PTC/Ion chromatography.
N-substituted (cis/trans) phenoxyalkylation using Michael reaction of complex amino acids
- a "alkane isomerisation" type of organic catalysis ? 1
- isopropanol can donate proton -- an aldehyde like solvent?
- alkane isomerisation = organic synthesis: L-dopamine, cyclohexylamine, etc..
- ethics of producing synthetic opioid receptor agonist compounds for human-specific psychotropic experiments?
Related chemicals
- Benzylamine
- Isopropanol
References
1. Kim J., Recent Advances in Asymmetric Phase-Transfer-Catalysis, 2011 http://stoltz.caltech.edu/seminars/2011_Kim.pdf p. [1-25]
See also
- Michael reaction
- Pictet-Spengler reaction
