Piperidine - Revision history

Etienne Robillard: /* Piperidine derivatives in nucleophilic ketol-enol (imine) substitutions */

2013-02-20T01:57:38Z

Piperidine derivatives in nucleophilic ketol-enol (imine) substitutions

←Older revision		Revision as of 01:57, 20 February 2013
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	* For DNA depurination with a 2-cyanoethyl hetero-aryl-alkyl moeity (ie: a N-methyl cyanide anion), see [[Ethanamine]]		* For DNA depurination with a 2-cyanoethyl hetero-aryl-alkyl moeity (ie: a N-methyl cyanide anion), see [[Ethanamine]]
-	* For in situ polymer-based drug delivery of phenethylamine substituted imines, see [[Phenethylamine]]	+	* For in situ polymer-based drug delivery of phenethylamine substituted imines, see [[Phenethylamine]] and [http://www.chemguide.co.uk/organicprops/haloalkanes/grignard.html Grignard reagents] .

	== See also ==		== See also ==

Etienne Robillard at 01:26, 20 February 2013

2013-02-20T01:26:57Z

←Older revision		Revision as of 01:26, 20 February 2013
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	* Stork-Enamine alkylation: http://en.wikipedia.org/wiki/Stork_enamine_alkylation		* Stork-Enamine alkylation: http://en.wikipedia.org/wiki/Stork_enamine_alkylation
		+
		+	=== Piperidine derivatives in nucleophilic ketol-enol (imine) substitutions ===
		+
		+	* For DNA depurination with a 2-cyanoethyl hetero-aryl-alkyl moeity (ie: a N-methyl cyanide anion), see [[Ethanamine]]
		+	* For in situ polymer-based drug delivery of phenethylamine substituted imines, see [[Phenethylamine]]

	== See also ==		== See also ==

	* [[THF]]		* [[THF]]
		+	* [[PVA]]
		+	* [[PEA]]

Etienne Robillard at 13:57, 18 January 2013

2013-01-18T13:57:19Z

←Older revision		Revision as of 13:57, 18 January 2013
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	* An important secondary amine used as precursor to alkylamines with a [http://en.wikipedia.org/wiki/Piperidine#Reactions aryl-ketone] (heteroarylalkyl) moeity when the reaction is performed in presence of a cyanide as the nitrogen substitution group .		* An important secondary amine used as precursor to alkylamines with a [http://en.wikipedia.org/wiki/Piperidine#Reactions aryl-ketone] (heteroarylalkyl) moeity when the reaction is performed in presence of a cyanide as the nitrogen substitution group .
-	* In organic ketone-amine reactions, piperidine may participate in [http://en.wikipedia.org/wiki/Hydrogenation_of_carbon-nitrogen_double_bonds hydrogenation of C=N double bounds] where the N-substituted chiral imine may be converted to a enamine, the tautomeric form of a imine. [http://en.wikipedia.org/wiki/Enamine 1]	+	* In organic [http://www.openwetware.org/wiki/Todd:Catalytic,_Asymmetric_Pictet-Spengler_Reaction ketone-amine reactions], piperidine may participate in [http://en.wikipedia.org/wiki/Hydrogenation_of_carbon-nitrogen_double_bonds hydrogenation of C=N double bounds] where the N-substituted chiral imine may be converted to a enamine, the tautomeric form of a imine. [http://en.wikipedia.org/wiki/Enamine 1]

	=== Reductive alkylation of N-aryl substituted imines via piperidine-derived enamines ===		=== Reductive alkylation of N-aryl substituted imines via piperidine-derived enamines ===

Etienne Robillard at 13:26, 17 January 2013

2013-01-17T13:26:20Z

←Older revision		Revision as of 13:26, 17 January 2013
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	* An important secondary amine used as precursor to alkylamines with a [http://en.wikipedia.org/wiki/Piperidine#Reactions aryl-ketone] (heteroarylalkyl) moeity when the reaction is performed in presence of a cyanide as the nitrogen substitution group .		* An important secondary amine used as precursor to alkylamines with a [http://en.wikipedia.org/wiki/Piperidine#Reactions aryl-ketone] (heteroarylalkyl) moeity when the reaction is performed in presence of a cyanide as the nitrogen substitution group .
	* In organic ketone-amine reactions, piperidine may participate in [http://en.wikipedia.org/wiki/Hydrogenation_of_carbon-nitrogen_double_bonds hydrogenation of C=N double bounds] where the N-substituted chiral imine may be converted to a enamine, the tautomeric form of a imine. [http://en.wikipedia.org/wiki/Enamine 1]		* In organic ketone-amine reactions, piperidine may participate in [http://en.wikipedia.org/wiki/Hydrogenation_of_carbon-nitrogen_double_bonds hydrogenation of C=N double bounds] where the N-substituted chiral imine may be converted to a enamine, the tautomeric form of a imine. [http://en.wikipedia.org/wiki/Enamine 1]
		+
		+	=== Reductive alkylation of N-aryl substituted imines via piperidine-derived enamines ===
		+
		+	* Stork-Enamine alkylation: http://en.wikipedia.org/wiki/Stork_enamine_alkylation

	== See also ==		== See also ==

	* [[THF]]		* [[THF]]

Etienne Robillard at 12:11, 17 January 2013

2013-01-17T12:11:28Z

←Older revision		Revision as of 12:11, 17 January 2013
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	* An important secondary amine used as precursor to alkylamines with a [http://en.wikipedia.org/wiki/Piperidine#Reactions aryl-ketone] (heteroarylalkyl) moeity when the reaction is performed in presence of a cyanide as the nitrogen substitution group .		* An important secondary amine used as precursor to alkylamines with a [http://en.wikipedia.org/wiki/Piperidine#Reactions aryl-ketone] (heteroarylalkyl) moeity when the reaction is performed in presence of a cyanide as the nitrogen substitution group .
-	* In organic ketone-amine reactions, piperidine may participate in [~~hydrogenation of C=N double bounds~~ http://en.wikipedia.org/wiki/Hydrogenation_of_carbon-nitrogen_double_bonds] where the N-substituted chiral imine may be converted to a enamine, the tautomeric form of a imine. [1]	+	* In organic ketone-amine reactions, piperidine may participate in [http://en.wikipedia.org/wiki/Hydrogenation_of_carbon-nitrogen_double_bonds hydrogenation of C=N double bounds] where the N-substituted chiral imine may be converted to a enamine, the tautomeric form of a imine. [http://en.wikipedia.org/wiki/Enamine 1]

	== See also ==		== See also ==

	* [[THF]]		* [[THF]]

Etienne Robillard at 12:10, 17 January 2013

2013-01-17T12:10:35Z

←Older revision		Revision as of 12:10, 17 January 2013
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-	* An important secondary amine used as precursor to alkylamines with a [http://en.wikipedia.org/wiki/Piperidine#Reactions aryl-ketone] (heteroarylalkyl) moeity when the	+	* An important secondary amine used as precursor to alkylamines with a [http://en.wikipedia.org/wiki/Piperidine#Reactions aryl-ketone] (heteroarylalkyl) moeity when the reaction is performed in presence of a cyanide as the nitrogen substitution group .
-	reaction is performed in presence of a cyanide as the nitrogen substitution group .	+	* In organic ketone-amine reactions, piperidine may participate in [hydrogenation of C=N double bounds http://en.wikipedia.org/wiki/Hydrogenation_of_carbon-nitrogen_double_bonds] where the N-substituted chiral imine may be converted to a enamine, the tautomeric form of a imine. [1]
-	* In organic ketone-amine reactions, piperidine may participate in [hydrogenation of C=N double bounds http://en.wikipedia.org/wiki/Hydrogenation_of_carbon-nitrogen_double_bonds] where	+
-	the N-substituted chiral imine may be converted to a enamine, the tautomeric form of a imine. [1]	+

	== See also ==		== See also ==

	* [[THF]]		* [[THF]]

Etienne Robillard at 12:10, 17 January 2013

2013-01-17T12:10:07Z

←Older revision		Revision as of 12:10, 17 January 2013
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-	An important secondary amine used as precursor to alkylamines with a [http://en.wikipedia.org/wiki/Piperidine#Reactions aryl-ketone] (heteroarylalkyl) moeity when the	+	* An important secondary amine used as precursor to alkylamines with a [http://en.wikipedia.org/wiki/Piperidine#Reactions aryl-ketone] (heteroarylalkyl) moeity when the
	reaction is performed in presence of a cyanide as the nitrogen substitution group .		reaction is performed in presence of a cyanide as the nitrogen substitution group .
		+	* In organic ketone-amine reactions, piperidine may participate in [hydrogenation of C=N double bounds http://en.wikipedia.org/wiki/Hydrogenation_of_carbon-nitrogen_double_bonds] where
		+	the N-substituted chiral imine may be converted to a enamine, the tautomeric form of a imine. [1]
		+
		+	== See also ==
		+
		+	* [[THF]]

Etienne Robillard: New page: An important secondary amine used as precursor to alkylamines with a [http://en.wikipedia.org/wiki/Piperidine#Reactions aryl-ketone] (heteroarylalkyl) moeity when the reaction is performed...

2013-01-07T12:32:01Z

New page: An important secondary amine used as precursor to alkylamines with a [http://en.wikipedia.org/wiki/Piperidine#Reactions aryl-ketone] (heteroarylalkyl) moeity when the reaction is performed...

New page

An important secondary amine used as precursor to alkylamines with a [http://en.wikipedia.org/wiki/Piperidine#Reactions aryl-ketone] (heteroarylalkyl) moeity when the
reaction is performed in presence of a cyanide as the nitrogen substitution group .