User:Etienne Robillard/Notebook/Piperidine

From OpenWetWare

(Difference between revisions)
Jump to: navigation, search
(One intermediate revision not shown.)
Line 1: Line 1:
* An important secondary amine used as precursor to alkylamines with a [http://en.wikipedia.org/wiki/Piperidine#Reactions aryl-ketone] (heteroarylalkyl) moeity when the reaction is performed in presence of a cyanide as the nitrogen substitution group .
* An important secondary amine used as precursor to alkylamines with a [http://en.wikipedia.org/wiki/Piperidine#Reactions aryl-ketone] (heteroarylalkyl) moeity when the reaction is performed in presence of a cyanide as the nitrogen substitution group .
-
* In organic ketone-amine reactions, piperidine may participate in [http://en.wikipedia.org/wiki/Hydrogenation_of_carbon-nitrogen_double_bonds hydrogenation of C=N double bounds] where the N-substituted chiral imine may be converted to a enamine, the tautomeric form of a imine. [http://en.wikipedia.org/wiki/Enamine 1]
+
* In organic [http://www.openwetware.org/wiki/Todd:Catalytic,_Asymmetric_Pictet-Spengler_Reaction ketone-amine reactions], piperidine may participate in [http://en.wikipedia.org/wiki/Hydrogenation_of_carbon-nitrogen_double_bonds hydrogenation of C=N double bounds] where the N-substituted chiral imine may be converted to a enamine, the tautomeric form of a imine. [http://en.wikipedia.org/wiki/Enamine 1]
 +
 
 +
=== Reductive alkylation of N-aryl substituted imines via piperidine-derived enamines ===
 +
 
 +
* Stork-Enamine alkylation: http://en.wikipedia.org/wiki/Stork_enamine_alkylation 
== See also ==
== See also ==
* [[THF]]
* [[THF]]

Revision as of 09:57, 18 January 2013

  • An important secondary amine used as precursor to alkylamines with a aryl-ketone (heteroarylalkyl) moeity when the reaction is performed in presence of a cyanide as the nitrogen substitution group .
  • In organic ketone-amine reactions, piperidine may participate in hydrogenation of C=N double bounds where the N-substituted chiral imine may be converted to a enamine, the tautomeric form of a imine. 1

Reductive alkylation of N-aryl substituted imines via piperidine-derived enamines

See also

Personal tools